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Considering that you have two types of battery bank chemistry and a single Quattro II 24V, you will have to VE.Config/configure the Inverter for one type battery bank. Unless they have the exact programme settings, then there MAY be some hard-wiring possibility to switch between the two banks. But from what I know, lead acid and lithium battery have different configuration settings, and therefore you would have to reprogramme everytime you switch from one battery bank to the other.
Configure the Quattro for the house bank as intended. Use an Orion 24/24-17 to charge starter bank from house bank. Normally you need a maintenance charge, not a rapid charge, so this would be adequate.
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